Can I use my ADP total pay card to deposit money on pokerstars?

My employer has given me an ADP TotalPay Card from moneynetwork for direct deposit of my paychecks. It has a STAR logo on the front in the bottom right and on the back in the bottom left, it has what appears to be the two mastercard logos. One says Maestro and the other says Cirrus. Not sure if all of that is relevent, but the additional information in regards to an accurate answer can't hurt. It came with like, 5 check things and whatnot. I've looked over the terms and conditions and couldn't find anything regarding its use for online gambling. Does anyone else have one of these cards and has successfully used it to deposit fund on Pokerstars or know if I'm able to?